Why does nh3 form coordination compounds
Commercial water softeners also use a complexing agent to treat hard water by passing the water over ion-exchange resins, which are complex sodium salts. When water flows over the resin, sodium ion is dissolved, and insoluble salts precipitate onto the resin surface.
Another application of complexing agents is found in medicine. Unlike x-rays, magnetic resonance imaging MRI can give relatively good images of soft tissues such as internal organs. MRI is based on the magnetic properties of the 1 H nucleus of hydrogen atoms in water, which is a major component of soft tissues. Because the properties of water do not depend very much on whether it is inside a cell or in the blood, it is hard to get detailed images of these tissues that have good contrast.
When a patient is injected with a paramagnetic metal cation in the form of a stable complex known as an MRI contrast agent, the magnetic properties of water in cells are altered. Because the different environments in different types of cells respond differently, a physician can obtain detailed images of soft tissues. The formation of complex ions can substantially increase the solubility of sparingly soluble salts if the complex ion has a large K f.
A complex ion is a species formed between a central metal ion and one or more surrounding ligands, molecules or ions that contain at least one lone pair of electrons. Small, highly charged metal ions have the greatest tendency to act as Lewis acids and form complex ions. The equilibrium constant for the formation of the complex ion is the formation constant K f. The formation of a complex ion by adding a complexing agent increases the solubility of a compound.
Learning Objectives To be introduced to complex ions, including ligands. The Effect of the Formation of Complex Ions on Solubility What happens to the solubility of a sparingly soluble salt if a ligand that forms a stable complex ion is added to the solution?
Calculate the solubility of AgCl in each situation: in pure water in 1. Add the two equations and calculate the equilibrium constant for the overall equilibrium. Write the equilibrium constant expression for the overall reaction.
Solve for the concentration of the complex ion. Answer 1. Summary The formation of complex ions can substantially increase the solubility of sparingly soluble salts if the complex ion has a large K f. Ammonia Complexes. Is there is any change in the oxidation state or charge of a central metal atom of the coordination complex? Rephrasing your question a bit: When ammonia is coordinated to say Co as in your example, does N of the NH3 gains the formal positive charge?
Formal charge is that, a formalism which tries to describe electron distribution in a molecule. Nature does not restrict electron distribution in whole numbers [1,2, etc. Sign up to join this community. The best answers are voted up and rise to the top. Stack Overflow for Teams — Collaborate and share knowledge with a private group. Create a free Team What is Teams? Learn more. Does N in NH3 ligand gains formal positive charge as N in ammonium ion?
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Solution :. Very Important Questions.
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